CobaltMaghrebV1, Main, Exploration, bibRecord, 001008

Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors

Identifieur interne : 001008 ( Main/Exploration ); précédent : 001007; suivant : 001009

Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors

Auteurs : R. Mlika [Tunisie] ; H. Ben Ouada [Tunisie] ; R. Ben Chaabane [Tunisie] ; M. Gamoudi [France] ; G. Guillaud [France] ; N. Jaffrezic-Renault [France] ; R. Lamartine [France]

Source :

Electrochimica Acta [ 0013-4686 ] ; 1996.

RBID : ISTEX:441E39F982E90D0F71E0D80F9B28CA207AA241DE

Abstract

Thin p-tert-butyl calix[4]arene and p-tert-butyl calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical microsensors based on an E.I.S. (Electrolyte-Insulator-Semiconductor) structure. Electrochemical capacity measurements were made to test and calibrate physico-chemical sensors with regards to their sensitivity and selectivity. The sensing properties of calix[4]arene and calix[6]arene towards alkaline and heavy metal ions were tested. Both devices have shown Nernstian response and a wide working pH range. The former responded well to sodium ions and the latter to nickel ions, thus partial selectivity for these ions is shown. The improved lifetime (compared with membranes prepared by physical adsorption techniques) and sensitivity observed for these films indicates that these structures are worthy of further developments.

Url:

https://api.istex.fr/document/441E39F982E90D0F71E0D80F9B28CA207AA241DE/fulltext/pdf

DOI: 10.1016/S0013-4686(97)00259-4

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 001001
to stream Istex, to step Curation: 000B38
to stream Istex, to step Checkpoint: 000849
to stream Main, to step Merge: 001047
to stream Main, to step Curation: 001008

Le document en format XML

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<front><div type="abstract" xml:lang="en">Thin p-tert-butyl calix[4]arene and p-tert-butyl calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical microsensors based on an E.I.S. (Electrolyte-Insulator-Semiconductor) structure. Electrochemical capacity measurements were made to test and calibrate physico-chemical sensors with regards to their sensitivity and selectivity. The sensing properties of calix[4]arene and calix[6]arene towards alkaline and heavy metal ions were tested. Both devices have shown Nernstian response and a wide working pH range. The former responded well to sodium ions and the latter to nickel ions, thus partial selectivity for these ions is shown. The improved lifetime (compared with membranes prepared by physical adsorption techniques) and sensitivity observed for these films indicates that these structures are worthy of further developments.</div>
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Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors

Calixarene membranes on semiconductor substrates for E.I.S. chemical sensors

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri